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Containing\\nN,N,N\u0027,N\u0027-Tetrakis[(1-methyl-2-benzimidazolyl)methyl]-\\n2-hydroxy-1,3-diaminopropane and a Thiocyanate Ion"], "weko_shared_id": -1}
Synthesis, Structures, and Magnetic Properties of\nDinuclear Nickel(II) Complexes Containing\nN,N,N',N'-Tetrakis[(1-methyl-2-benzimidazolyl)methyl]-\n2-hydroxy-1,3-diaminopropane and a Thiocyanate Ion
https://cur-ren.repo.nii.ac.jp/records/170
https://cur-ren.repo.nii.ac.jp/records/17005bf2aef-9897-4680-a7f0-c6cde58705e4
名前 / ファイル | ライセンス | アクション |
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7_011_017.pdf (842.7 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2018-10-04 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Synthesis, Structures, and Magnetic Properties of\nDinuclear Nickel(II) Complexes Containing\nN,N,N',N'-Tetrakis[(1-methyl-2-benzimidazolyl)methyl]-\n2-hydroxy-1,3-diaminopropane and a Thiocyanate Ion | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Dinuclear nickel(II) complexes | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Magnetic susceptibilities | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Crystal structures | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Dinuclear nickel(II) complexes | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Magnetic susceptibilities | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Crystal structures | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
著者 |
中尾, 安男
× 中尾, 安男× Sato, Tomohiko× Mori, Wasuke× Goto, Shiko× Issiki, Miwa× Fujii, Mie× Motoo, Shiro× Tanaka, Rika× Matsumoto, keiji× Nakao, Yasuo× Sato, Tomohiko× Mori, Wasuke× Goto, Shiko× Issiki, Miwa× Fujii, Mie× Motoo, Shiro× Tanaka, Rika× Matsumoto, keiji |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Three dinuclear nickel(II) complexes, [Ni2(L-Me)(NCS)(H2O)3](PF6)2 (1), [Ni2(L-Me)(NCS)2 (CH3OH) (H2O)]PF6 (2), and [Ni2(L-Me)(NCS)2(H2O)2]NCS (3) containing HL-Me(HL-Me = N,N,N',N'-tetrakis[(1-methyl-2-benzimidazolyl)methyl]-2-hydroxy-1,3-diaminopropane) have been synthesized and characterized by their IR and UV-Vis spectra and magnetic susceptibilities. The crystal structures of the complexes 1’, 2’, and 3’, from which 1, 2, and 3, respectively, are derived, were determined by X-ray crystallography. These complexes are dimeric and only an alkoxo of L-Me- bridges two octahedral Ni(II) ions. While 2’ and 3’ have symmetrical conformations of L-Me-, that of 1’ is unsymmetrical. Magnetic susceptibility measurements from liquid helium temperature to room temperature showed a weak ferromagnetic exchange coupling between the two nickel(II) ions (2J =7.8cm-1, H =-2JS1・S2) for 1. On the other hand, antiferromagnetic interactions were observed for 2 and 3 (2J =-29.2and -27.8cm-1, respectively). |
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書誌情報 |
Chugokugakuen journal 巻 7, p. 11-17, 発行日 2008 |
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出版者 | ||||||
出版者 | 中国学園大学/中国短期大学 | |||||
出版者(英) | ||||||
en | ||||||
Chugokugakuen University / Chugoku Junior Cllege | ||||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1348-1452 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11806612 | |||||
論文ID(NAID) | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | NAID | |||||
関連識別子 | 110007124436 | |||||
権利 | ||||||
権利情報 | 中国学園大学/中国短期大学 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
日本十進分類法 | ||||||
主題Scheme | NDC | |||||
主題 | 430 |