{"created":"2023-05-15T11:33:54.305413+00:00","id":170,"links":{},"metadata":{"_buckets":{"deposit":"8774859b-f57d-42df-b9f5-82e449b7a58c"},"_deposit":{"created_by":2,"id":"170","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"170"},"status":"published"},"_oai":{"id":"oai:cur-ren.repo.nii.ac.jp:00000170","sets":["2:6:9"]},"author_link":["7484","7485","7488","7497","7500","7501","7491","7493","7492","7494","7487","7495","7496","7498","7499","7486","7490","7489"],"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"17","bibliographicPageStart":"11","bibliographicVolumeNumber":"7","bibliographic_titles":[{"bibliographic_title":"Chugokugakuen journal"}]}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Three dinuclear nickel(II) complexes, [Ni2(L-Me)(NCS)(H2O)3](PF6)2 (1), [Ni2(L-Me)(NCS)2 (CH3OH) (H2O)]PF6 (2), and [Ni2(L-Me)(NCS)2(H2O)2]NCS (3) containing HL-Me(HL-Me ＝ N,N,N',N'-tetrakis[(1-methyl-2-benzimidazolyl)methyl]-2-hydroxy-1,3-diaminopropane) have been synthesized and characterized by their IR and UV-Vis spectra and magnetic susceptibilities. The crystal structures of the complexes\n1’, 2’, and 3’, from which 1, 2, and 3, respectively, are derived, were determined by X-ray crystallography. These complexes are dimeric and only an alkoxo of L-Me－ bridges two octahedral Ni(II) ions. While 2’ and 3’ have symmetrical conformations of L-Me－, that of 1’ is unsymmetrical. Magnetic susceptibility measurements from liquid helium temperature to room temperature showed a\nweak ferromagnetic exchange coupling between the two nickel(II) ions (2J ＝7.8cm－1, H ＝－2JS1・S2) for 1. On the other hand, antiferromagnetic interactions were observed for 2 and 3 (2J ＝－29.2and －27.8cm－1, respectively).","subitem_description_type":"Abstract"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"中国学園大学/中国短期大学"}]},"item_10002_relation_12":{"attribute_name":"論文ID（NAID）","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"110007124436","subitem_relation_type_select":"NAID"}}]},"item_10002_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"中国学園大学/中国短期大学"}]},"item_10002_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11806612","subitem_source_identifier_type":"NCID"}]},"item_10002_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1348-1452","subitem_source_identifier_type":"ISSN"}]},"item_10002_subject_21":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"430","subitem_subject_scheme":"NDC"}]},"item_10002_text_24":{"attribute_name":"出版者（英）","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Chugokugakuen University / Chugoku Junior Cllege"}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"中尾, 安男"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sato, Tomohiko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Mori, Wasuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Goto, Shiko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Issiki, Miwa"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fujii, Mie"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Motoo, Shiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tanaka, Rika"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsumoto, keiji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nakao, Yasuo","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sato, Tomohiko","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Mori, Wasuke","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Goto, Shiko","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Issiki, Miwa","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fujii, Mie","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Motoo, Shiro","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tanaka, Rika","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsumoto, keiji","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-10-04"}],"displaytype":"detail","filename":"7_011_017.pdf","filesize":[{"value":"842.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"7_011_017.pdf","url":"https://cur-ren.repo.nii.ac.jp/record/170/files/7_011_017.pdf"},"version_id":"fb92568e-e1c0-4b07-a257-7c335cad685a"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Dinuclear nickel(II) complexes","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Magnetic susceptibilities","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Crystal structures","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Dinuclear nickel(II) complexes","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Magnetic susceptibilities","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Crystal structures","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis, Structures, and Magnetic Properties of\\nDinuclear Nickel(II) Complexes Containing\\nN,N,N',N'-Tetrakis[(1-methyl-2-benzimidazolyl)methyl]-\\n2-hydroxy-1,3-diaminopropane and a Thiocyanate Ion","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis, Structures, and Magnetic Properties of\\nDinuclear Nickel(II) Complexes Containing\\nN,N,N',N'-Tetrakis[(1-methyl-2-benzimidazolyl)methyl]-\\n2-hydroxy-1,3-diaminopropane and a Thiocyanate Ion","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"2","path":["9"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-10-04"},"publish_date":"2018-10-04","publish_status":"0","recid":"170","relation_version_is_last":true,"title":["Synthesis, Structures, and Magnetic Properties of\\nDinuclear Nickel(II) Complexes Containing\\nN,N,N',N'-Tetrakis[(1-methyl-2-benzimidazolyl)methyl]-\\n2-hydroxy-1,3-diaminopropane and a Thiocyanate Ion"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-15T11:53:37.899030+00:00"}