@article{oai:cur-ren.repo.nii.ac.jp:00000170,
 author = {中尾, 安男 and Sato, Tomohiko and Mori, Wasuke and Goto, Shiko and Issiki, Miwa and Fujii, Mie and Motoo, Shiro and Tanaka, Rika and Matsumoto, keiji and Nakao, Yasuo and Sato, Tomohiko and Mori, Wasuke and Goto, Shiko and Issiki, Miwa and Fujii, Mie and Motoo, Shiro and Tanaka, Rika and Matsumoto, keiji},
 journal = {Chugokugakuen journal},
 month = {},
 note = {Three dinuclear nickel(II) complexes, [Ni2(L-Me)(NCS)(H2O)3](PF6)2 (1), [Ni2(L-Me)(NCS)2 (CH3OH) (H2O)]PF6 (2), and [Ni2(L-Me)(NCS)2(H2O)2]NCS (3) containing HL-Me(HL-Me ＝ N,N,N',N'-tetrakis[(1-methyl-2-benzimidazolyl)methyl]-2-hydroxy-1,3-diaminopropane) have been synthesized and characterized by their IR and UV-Vis spectra and magnetic susceptibilities. The crystal structures of the complexes
1’, 2’, and 3’, from which 1, 2, and 3, respectively, are derived, were determined by X-ray crystallography. These complexes are dimeric and only an alkoxo of L-Me－ bridges two octahedral Ni(II) ions. While 2’ and 3’ have symmetrical conformations of L-Me－, that of 1’ is unsymmetrical. Magnetic susceptibility measurements from liquid helium temperature to room temperature showed a
weak ferromagnetic exchange coupling between the two nickel(II) ions (2J ＝7.8cm－1, H ＝－2JS1・S2) for 1. On the other hand, antiferromagnetic interactions were observed for 2 and 3 (2J ＝－29.2and －27.8cm－1, respectively).},
 pages = {11--17},
 title = {Synthesis, Structures, and Magnetic Properties of\nDinuclear Nickel(II) Complexes Containing\nN,N,N',N'-Tetrakis[(1-methyl-2-benzimidazolyl)methyl]-\n2-hydroxy-1,3-diaminopropane and a Thiocyanate Ion},
 volume = {7},
 year = {2008}
}